Electron Affinity Values

Electron affinity values defines the energy change due to addition of an electron to a gaseous atom. Each element has distinct electron affinity value. The general description of electron affinity value of each kind of element is given below:

  • Electron affinities of noble gases are generally considered to be zero.
  • Electron affinities of alkaline earth metals are negative.
  • Nonmetals generally have higher electron affinities compared to metals.

Electron affinity of few of the common elements are described below:

Electron Affinity of Oxygen

Electron affinity of oxygen is the energy released when an electron is added to an isolated gaseous oxygen atom. The measurement of the electron affinity of oxygen is 1.46 eV. This value indicates the energy released when an electron is added to form O.

The first electron affinity of oxygen is -142 kJ mol-1, which is lower than that of fluorine, indicating that oxygen has a lower tendency to accept an electron than fluorine.

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Electron Affinity of Chlorine

Electron affinity of Chlorine is -349 kJ/mol. This value indicates the energy released when an electron is added to form Cl. Chlorine’s high electron affinity is related to its position in the halogen group, which has the highest electron affinities among all elements.

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Electron Affinity of Fluorine

Electron affinity of fluorine is -328 kJ/mol. This negative value indicates that energy is released when an electron is gained by a fluorine atom, as there is an attraction between the protons in the nucleus and the added electron.

Fluorine’s high electron affinity is due to its small size, which brings the incoming electron closer to the nucleus, resulting in a strong attraction.

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Electron Affinity

Electron Affinity is a measure of the attraction between an incoming electron and the nucleus of an atom or molecule. It is defined as the change in energy (in kJ/mole) of a neutral atom (in the gaseous phase) when an electron is added to the atom.

In this article, we will look into what electron affinity is, its periodic trends, the factors affecting electron affinity, and the values of electron affinity of different elements.

Table of Content

  • What is Electron Affinity?
  • Trends in Electron Affinity
  • Types of Electron Affinity
  • Factors Affecting Electron Affinity
  • Electron Affinity Vs Ionization Energy

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What is Electron Affinity?

Electron affinity is the energy change that occurs when an electron is added to a neutral atom to form a negatively charged ion. It measures the attraction between the incoming electron and the nucleus, with a more negative value indicating a higher affinity for electrons....

Trends in Electron Affinity

Trends in electron affinity refers to the change in value of electron affinity as we move across the periodic table. The electron affinity depends upon the nuclear charge and atomic size. Electron affinity is directly proportional to the nuclear charge on the atom and inversely proportional to its atomic size. Hence we can conclude:...

Types of Electron Affinity

Electron affinity can be classified into two types:...

Electron Affinity Values

Electron affinity values defines the energy change due to addition of an electron to a gaseous atom. Each element has distinct electron affinity value. The general description of electron affinity value of each kind of element is given below:...

Factors Affecting Electron Affinity

Various factors that affect the Electron affinity are as follows:...

Electron Affinity of Halogens

Electron affinity of halogens decreases as you move down the group, with fluorine having the highest electron affinity and astatine having the lowest. The trends in electron affinity for halogens can be summarized as follows:...

Electron Affinity of Metals and Non-Metals

Metals have a lower electron affinity than non-metals, as they lose valence electrons to form cations and require energy to gain electrons. On the other hand, non-metals have a higher electron affinity, indicating a greater tendency to gain electrons to form anions and release energy in the process....

Electron Affinity Vs Ionization Energy

The difference between electron affinity and ionization energy is given below:...

Electron Affinity: Frequently Asked Questions

What is Electron Affinity?...