Uses of Potassium Hexacyanoferrate III

  • This compound is used as a mild oxidizing agent in organic chemistry. 
  • It is used in calico printing and wool dyeing. 
  • It is also used to harden iron and steel. 
  • It is used as a laboratory reagent and in electroplating. 
  • Potassium ferricyanide is widely used in photography and blueprint drawing.
  • It is used to formulate Murakami’s etchant, which is used by metallographers. Murakami’s etchant is formed when potassium hexacyanoferrate III is mixed with potassium hydroxide (or sodium hydroxide as a substitute) and water.

Potassium Hexacyanoferrate III Formula

Potassium hexacyanoferrate (III) is also termed Red prussiate of Potash or Potassium ferricyanide whose chemical formula is K3[Fe(CN)6]. It was discovered by Leopold Gmelin in the year 1822. Potassium Hexacyanoferrate III is composed of potassium, iron, carbon, and nitrogen elements. It appears as deep red crystals, which decompose on heating. This compound contains the octahedrally coordinated [Fe(CN)6]3− ion. It is soluble in water and its solution exhibits slight green-yellow fluorescence. When it reacts with a strong acid, highly toxic hydrogen cyanide gas is evolved. It is prepared when chlorine is passed through a solution of potassium ferrocyanide. Potassium ferricyanide is widely used in photography and blueprint drawing. It is also used in calico printing, electroplating, and wool dyeing, as a laboratory reagent, and as an oxidant in organic chemistry. It is used to formulate Murakami’s etchant, which is used by metallographers.

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Structure of Potassium Hexacyanoferrate (III)

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Preparation of Potassium Hexacyanoferrate (III)

When chlorine is passed through a solution of potassium ferrocyanide, potassium Hexacyanoferrate III is produced....

Physical Properties of Potassium Hexacyanoferrate (III)

Chemical Formula  K3[Fe(CN)6]  Other Names Potassium ferricyanide, Red prussiate of Potash,Prussian red Molar Mass 329.24 g/mol Appearance Deep red crystals Density 1.89 g/cm3 Melting Point 300 °C Boiling Point Decomposes Solubility Soluble in water, acid, and slightly soluble in alcohol...

Chemical Properties of Potassium Hexacyanoferrate (III)

When potassium hexacyanoferrate (III) reacts with a strong acid, highly toxic hydrogen cyanide gas is evolved....

Uses of Potassium Hexacyanoferrate III

This compound is used as a mild oxidizing agent in organic chemistry.  It is used in calico printing and wool dyeing.  It is also used to harden iron and steel.  It is used as a laboratory reagent and in electroplating.  Potassium ferricyanide is widely used in photography and blueprint drawing. It is used to formulate Murakami’s etchant, which is used by metallographers. Murakami’s etchant is formed when potassium hexacyanoferrate III is mixed with potassium hydroxide (or sodium hydroxide as a substitute) and water....

Health Hazards of Potassium Hexacyanoferrate (III)

Potassium hexacyanoferrate III is harmful if swallowed or inhaled.  Potassium hexacyanoferrate III is low toxic but causes mild irritation to the eyes, skin, and respiratory tract.  Potassium hexacyanoferrate III upon heating emits irritating or toxic fumes....

FAQs on Potassium Hexacyanoferrate (III)

Question 1: How is Potassium hexacyanoferrate (III) prepared?...