Arrhenius Theory of Electrolytic Dissociation

Arrhenius Theory of Electrolytic dissociation states that the aqueous solution of acid conducts electricity when a substance called electrolyte is dissolved in the solution, which further dissociates into ions and conducts electricity.

Dissociation is the process of dissolving substances into smaller parts that can reassemble in other circumstances. The compound’s molecules disintegrate into ions (electrically charged particles) in an ionic or electrolytic dissociation process that involves the addition of an electrolyte or solvent.

Water being a neutral substance does not conduct electricity. But when an electrolyte (such as salt) is dissolved in water, it conducts electricity. This process is known as “Electrolytic Dissociation“.

The electrolytic dissociation of a substance further depends on the nature of the electrolyte. The electrolytes are of basically two types namely:

  • Strong Electrolytes
  • Weak Electrolytes

Strong Electrolytes

Strong Electrolytes are those that can totally breakdown into their corresponding ions even in mild circumstances.

  • Its dissociation constant is also large, indicating a high degree of dissociation.
  • Electrical conductivity is very high in this kind of electrolytes.

Weak Electrolytes

Weak electrolytes can only partially dissociate in an aqueous solution.

  • Low ionization and a lower dissociation constant value are characteristics of these electrolytes.
  • Electrical conductivity is poor in them.

Arrhenius Theory

Arrhenius Theory introduced in 1887 by Swedish scientist Svante Arrhenius, is used to describe the behavior of acids and bases in aqueous solutions. This theory states that a material that releases hydroxide ions (OH–) in water is an Arrhenius base, and a substance that releases hydrogen ions (H+) in water is an Arrhenius acid.

This article will thoroughly explain the Arrhenius theory, along with instances of Arrhenius bases, Arrhenius acids and Arrhenius theory of electrolytic dissociation.

Table of Content

  • What is Arrhenius Theory?
  • Arrhenius Theory of Acid and Base
  • Reaction Between Arrhenius Acid and Base
  • Arrhenius Theory of Electrolytic Dissociation
  • Limitations of Arrhenius Theory

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What is Arrhenius Theory?

Arrhenius theory was introduced by a Swedish chemist Svante Arrhenius in 1884. This theory takes into account how acids and bases dissociate in water to explain their behaviour in aqueous solutions....

Arrhenius Theory of Acid and Base

Arrhenius theory particularly focus on the acidic or basic behavior of a substance. As per this theory, the substances that dissociate in water to release hydrogen ions (H+) are called acids, whereas the substances that dissociate in water to release hydroxide ions (OH–) are called bases....

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A neutralization reaction occurs when an Arrhenius acid and an Arrhenius base interact. The hydroxide ions (OH−) from the base and the hydrogen ions (H+) from the acid which mix to generate water in a neutralization process. Furthermore, the negative ion from the acid and the positive ion from the base combine to create a salt....

Arrhenius Theory of Electrolytic Dissociation

Arrhenius Theory of Electrolytic dissociation states that the aqueous solution of acid conducts electricity when a substance called electrolyte is dissolved in the solution, which further dissociates into ions and conducts electricity....

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Following are the limitations to the Arrhenius’s theory:...

Summary of Arrhenius Theory

We can summarize the whole Arrhenius’s theory in the following points:...

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